全文获取类型
收费全文 | 12033篇 |
免费 | 1876篇 |
国内免费 | 1079篇 |
专业分类
化学 | 8677篇 |
晶体学 | 83篇 |
力学 | 1582篇 |
综合类 | 208篇 |
数学 | 808篇 |
物理学 | 3630篇 |
出版年
2024年 | 21篇 |
2023年 | 164篇 |
2022年 | 340篇 |
2021年 | 484篇 |
2020年 | 554篇 |
2019年 | 465篇 |
2018年 | 439篇 |
2017年 | 483篇 |
2016年 | 652篇 |
2015年 | 566篇 |
2014年 | 674篇 |
2013年 | 1292篇 |
2012年 | 756篇 |
2011年 | 735篇 |
2010年 | 541篇 |
2009年 | 599篇 |
2008年 | 605篇 |
2007年 | 703篇 |
2006年 | 629篇 |
2005年 | 541篇 |
2004年 | 480篇 |
2003年 | 436篇 |
2002年 | 391篇 |
2001年 | 280篇 |
2000年 | 289篇 |
1999年 | 251篇 |
1998年 | 231篇 |
1997年 | 195篇 |
1996年 | 136篇 |
1995年 | 163篇 |
1994年 | 105篇 |
1993年 | 127篇 |
1992年 | 104篇 |
1991年 | 82篇 |
1990年 | 68篇 |
1989年 | 44篇 |
1988年 | 49篇 |
1987年 | 45篇 |
1986年 | 36篇 |
1985年 | 45篇 |
1984年 | 31篇 |
1983年 | 20篇 |
1982年 | 26篇 |
1981年 | 16篇 |
1980年 | 16篇 |
1979年 | 15篇 |
1978年 | 11篇 |
1976年 | 10篇 |
1974年 | 7篇 |
1973年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 47 毫秒
951.
Xin?YangEmail author Mali?Gong Lei?Huang Ping?Yan Haitao?Zhang 《Optical and Quantum Electronics》2004,36(12):1079-1088
In this paper, the authors investigate the performance of recently presented run-length limited (4, 18) code for high density optical storage systems. The construction of the code is described simply. The code has code rate R = 1/3 and density ratio (DR) = 1.67. The bit error rate (BER) performance for decision feedback equalizer (DFE) and partial response maximum likelihood (PRML) detector are simulated, considering signal-to-noise ratio (SNR) and optical channel jitter. The result shows that the performance of the code is acceptable. The encoder and decoder of the code are implemented by complex programmable logic device (CPLD) chip and the hardware resources required for encoder and decoder arelow. 相似文献
952.
Elastic friction drive of surface acoustic wave motor 总被引:2,自引:0,他引:2
Importance of elastic deformation control to obtain large output force with a surface acoustic wave (SAW) motor is discussed in this paper. By adding pre-load to slider, stator and slider surfaces are deformed in a few tens nanometer. Appropriate deformation in normal direction against normal vibration displacement amplitude of SAW existed. By moderate deformation, the output force of the SAW motor was enlarged up to about 10 N and no-load speed was 0.7 m/s. To produce this performance, the transducer weight and slider size were only 4.2 g and 4 x 4 mm(2).By traveling wave propagation, surface particles of the SAW device move in elliptical motion. Due to the amplitude of the elliptical motion is 10 or 20 nm order, the contact condition of the slider is very critical. To control the contact condition, namely, the elastic deformation of the slider and stator surface in nanometer order, a lot of projections were fabricated on the slider surface. The projection diameter was 20 micro m. In static condition, the elastic deformation and stress were evaluated with the FEM analysis. From this calculation and the simulation result, it is consider that the wave crest is distorted, hence the elasticity has influence on the friction drive condition.Elastic deformation of the stator surface beneath the projection from the initial position were evaluated. In 4 x 4 mm(2) square area, the sliders had from 1089 to 23,409 projections. Depression was independent to the contact pressure. However, the output force depended on the depression although the projection density were different. From the view point of the output power of the motor, the proper depression was independent to the projection density. Around 25 nm depression, the output force and output power were maximized. This depression value was almost same as the vibration displacement amplitude of the stator transducer. 相似文献
953.
Based on the theories of nonlinear continuum mechanics, piezoelectricity and elastic waves in solids, theoretical analysis of Bleustein-Gulyaev surface acoustic wave propagation in a prestressed layered piezoelectric structure are described. Numerical calculations are performed for the case that the layer and the substrate are identical LiNbO(3) except that they are polarized in opposite directions. It is found that an almost linear behavior of the relative change in phase velocity versus the initial stress is obtained for both surface electrically free and shorted cases. Potential applications in the design of acoustic wave devices are suggested. 相似文献
954.
955.
文章介绍了我国生物学家汤佩松先生和理论物理学家王竹溪先生42年前在植物生理学方面作出的一项具有重要历史意义的贡献.他们于1941年先于西方科学家二十多年提出解释植物细胞水分关系的热力学理论,首先引入了水势概念.然而这项贡献一直被埋没四十多年才得到承认.文章分析了汤佩松和王竹溪先生工作的内容、历史地位及其产生的背景,讨论了其在国内外的遭遇的原因及今日应当从中记取的教训. 相似文献
956.
Botta M Aime S Barge A Bobba G Dickins RS Parker D Terreno E 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(9):2102-2109
The (1)H and (17)O NMR relaxometric properties of two cationic complexes formed by Gd(III) with a macrocyclic heptadentate triamide ligand, L(1), and its Nmethylated analogue, L(2), have been investigated in aqueous media as a function of pH, temperature and magnetic field strength. The complexes possess two water molecules in their inner coordination sphere for which the rate of exchange has been found to be sensibly faster for the Nmethylated derivative and explained in terms of electronic effects (decrease of the charge density at the metal center) and perturbation of the network of hydrogen-bonded water molecules in the outer hydration sphere. The proton relaxivity shows a marked dependence from pH and decreases of about six units in the pH range 6.5 to 9.0. This has been accounted for by the displacement of the two water molecules by dissolved carbonate which acts as a chelating anion. The formation of ternary complexes with lactate, malonate, citrate, acetate, fluoride and hydrogenphosphate has been monitored by (1)H NMR relaxometric titrations at 20 MHz and pH 6.3 and the value of the affinity constant, K, and of the relaxivity of the adducts could be obtained. Lactate, malonate and citrate interact strongly with the complexes (log K > or =3.7) and coordinate in a bidendate mode by displacing both water molecules. Larger affinity constants have been measured for GdL(2). Acetate, fluoride and hydrogenphosphate form monoaqua ternary complexes which were investigated in detail with regard to their relaxometric properties. The NMR dispersion (NMRD) profiles indicate a large contribution to the relaxivity of the adducts from water molecules belonging to the second hydration shell of the complexes and hydrogen-bonded to the anion. A VT (17)O NMR study has shown a marked increase of the rate of water exchange upon binding which is explained by coordination of the anion in an equatorial site, thus leaving the water molecule in an apical position, more accessible for interactions with the solvent molecules of the second hydration shell which facilitate the exchange process. 相似文献
957.
M. Iijima T. Hatakeyama M. Takahashi H. Hatakeyama 《Journal of Thermal Analysis and Calorimetry》2001,64(2):617-627
Application of thermomechanometry to the measurement of hydrogels containing a large amount of water was carried out by static
and dynamic methods. A thermomechanical analyzer (TMA) equipped with a quartz compression probe immersed in water was used.
Polysaccharide hydrogels containing ca 98% water were measured. Creep of hydrogels in water was analyzed in a stress range
from 1.04⋅103 to 5.2⋅103 Pa and loading rate from 0.3⋅103 to 3.0⋅103 Pa min−1.Stress relaxation was measured in compressed ratio range from 0.02 to 0.45 m m−1 and in compressing rate was 0.09 to 0.15 m m−1 min−1. Dynamic viscoelasticity was measured by TMA when dynamic Young’s modulus which was larger than 1⋅104 Pa in frequencies ranging from 0.02~0.2 Hz.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
958.
Franç ois Germinet Abel Klein 《Proceedings of the American Mathematical Society》2003,131(3):911-920
We study the decay at large distances of operator kernels of functions of generalized Schrödinger operators, a class of semibounded second order partial differential operators of mathematical physics, which includes the Schrödinger operator, the magnetic Schrödinger operator, and the classical wave operators (i.e., acoustic operator, Maxwell operator, and other second order partial differential operators associated with classical wave equations). We derive an improved Combes-Thomas estimate, obtaining an explicit lower bound on the rate of exponential decay of the operator kernel of the resolvent. We prove that for slowly decreasing smooth functions the operator kernels decay faster than any polynomial.
959.
Schleifer KJ 《Journal of computer-aided molecular design》2000,14(5):467-475
This paper describes the generation of a pseudoreceptor model for ryanodine receptor (RyR) modulating ryanoids in rabbit skeletal muscle. For this purpose, the molecular modelling software PrGen was applied to correlate experimentally determined and calculated free energies of binding for a set of 15 ryanodine derivatives. The final model indicates a narrow cleft with hydrogen bond donor and acceptor capacities (represented by an Asn) as most crucial for binding the pyrrole carboxylate substituent at C3 of ryanodine. In addition, hydrophobic residues flank the aromatic pyrrole ring (Tyr, Phe, and Ile). Two of those residues (Tyr and Ile) interact with the 2-isopropyl moiety, which seems to contribute to binding. Opposite to the pyrrole locus, a second hydrophobic region (represented by a Leu) restricts ryanodine derivatives in their longitudinal axis and leads to the discrimination of equatorial and axial positioned methyl groups and of polar substituents at C9. Finally, a charged glutamate residue generates strong hydrogen bonding and electrostatic interactions with the hydroxyl groups at C10 and C15. For this binding-site model – composed of six amino acid residues – a correlation for the training set ligands of R = 0.99 (Q2 = 0.975) and a root mean square (rms) deviation of 0.568 kcal/mol for the prediction of the binding energies of four test set ligands was obtained. Based on this pseudoreceptor model the putative topology of the real binding site of ryanoids will be discussed. 相似文献
960.
ZhuJianxin 《高校应用数学学报(英文版)》2000,15(4):443-452
In this paper, a local orthogonal transformation is created to transform the Helmholtz waveguide with curved interface to the one with a flat interface within the two-layer medium, and the Helmholtz equation uxx uzz k^2(x,z)u=0 is transformed to Vxx αVzz βVz γV=0. Numerical results demonstrate that the transformation is more feasible. This transformation is particularly useful for the research on wave propagation in acoustic waveguide. 相似文献